Military vets were everywhere in the 1960s and 70s, plenty of guys who were comfortable with a harness and rip cord.
The big question is the 727 knowledge, and considering the FBI probably investigated Boeing employees and past employees during the original investigation, I would guess Cooper just got lucky with the aft stairs not having a lock. I know we've had good discussions on it, and at first I thought Cooper had to have intimate knowledge of the 727, now I think otherwise.
So, remove the 727 requisite, and you are left with someone who worked in the chemical industry who had served in the military somewhere between WWII and Vietnam. In WWII, there were 16 million US veterans, of whom at least 20,000 were paratroopers (I can't find exact figures, but 13000 men dropped on d-day, and tens of thousands more dropped in Operation Market Garden. Between the Canadians and the Americans, I would wager you have at least 50k paratroopers. Add in the hundreds of thousands of Army Air Corps vets, and suddenly it doesn't look so unlikely.)